Forensic Identification of Air Freshener Components from the Toxicological Samples by GC-MS : A Case Report
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Abstract
Indoor air fresheners are commonly used to deodorize rooms and cars. A case of air freshener intoxication by oral ingestion was forwarded to the forensic laboratory to determine the components and cause of death.
The presumptive tests were conducted for organo-phosphorus and organo-chloro compounds, formaldehyde, carbolic acid, drugs and aromatic compounds. Gas Chromatography–Mass Spectroscopy (GC-MS) was used as a confirmatory test for all these compounds. Presence of toxic substances like dichlorvos (2,2 di-chlorovinyl dimethyl phosphate), phenol, formaldehyde, naphthalene was confirmed in the air freshener that led to the person’s death. Laboratory analysis also confirmed the presence of alprazolam in the viscera as per case history.
The methodology used can be utilized as a reference for TLC and GC-MS based analysis of such cases
Keywords
Air Fresheners, Toxicology, Mass Spectroscopy, Forensic Science, Suicide, Poison
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References
McMath R. Whether the Cover or Kill, Air fresheners smell like big business, Brandweek. 1993;34(8):34.
Material Safety Data Sheet (MSDS), Bad Air Sponge®" (PDF), Mateson Chemical Corporation. 2007.
Amoore JE, Hautala E. Odor as an aid to chemical safety: Odor thresholds compared with threshold limit values and volatiles for 214 industrial chemicals in air and water dilution. J Appl Toxicology. 1983;3(6):272-90. https://doi.org/10.1002/jat.2550030603
Mohammed B, Yakasai UA. Subacute toxicity study of some brands of air fresheners sold in Kano on Swiss albino rats (Rattus norvegicus). Intl J Adv Acad Res| Sci, Technol & Engineer. 2017;3:19-32.
Steinemann AC. Fragranced consumer products and undisclosed ingredients. Environmental Impact Assessment Review. 2009 Jan 1;29(1):32-8. https://doi.org/10.1016/j.eiar.2008.05.002
Kim S, Hong SH, Bong CK, Cho MH. Characterization of air freshener emission: the potential health effects. The Journal of toxicological sciences. 2015 Oct 1;40(5):535-50. https://doi.org/10.2131/jts.40.535
Anderson RC, Anderson JH. Toxic effects of air freshener emissions. Archives of Environmental Health: An International Journal. 1997 Nov 1;52(6):433-41. https://doi.org/10.1080/00039899709602222
Anderson RC, Anderson JH. Respiratory toxicity of mattress emissions in mice. Archives of Environmental Health: An International Journal. 2000 Jan 1;55(1):38-43. https://doi.org/10.1080/00039890009603383
Choi H, Schmidbauer N, Sundell J, Hasselgren M, Spengler J, Bornehag CG. Common household chemicals and the allergy risks in pre-school age children. PloS one. 2010 Oct 18;5(10):e13423. https://doi.org/10.1371/journal.pone.0013423
Hitosugi M, Tsukada C, Yamauchi S, Matsushima K, Furukawa S, Morita S, Nagai T. An autopsy case of fatal repellent air freshener poisoning. Legal Medicine. 2015 Sep 1;17(5):360-3. https://doi.org/10.1016/j.legalmed.2015.04.004
Clarke EG. Isolation and identification of drugs in Pharmaceuticals, body fluids, and post-mortem material. Vol. 2. The Pharmaceutical Press, 17 Bloomsbury Square, London WC1A2NN.; 1975.
Directorate of forensic science: Laboratory manual: Selective and Scientific books publishers: revised 2005:64, 69, 119.
Potera C. Indoor air quality: scented products emit a bouquet of VOCs.
Reddy KSN, Murty OP. The essentials of Forensic Medicine and Toxicology: 33rdedition. 2014:500-598.
Farrow A, Taylor H, Northstone K, Golding J. Symptoms of mothers and infants related to total volatile organic compounds in household products. Archives of Environmental Health: An International Journal. 2003 Oct 1;58(10):633-41. https://doi.org/10.3200/AEOH.58.10.633-641
Caress SM, Steinemann AC. National prevalence of fragrance sensitivity. J Environ Health. 2009;71:46-50.
Steinemann A. Fragranced consumer products: exposures and effects from emissions. Air Quality, Atmosphere & Health. 2016 Dec 1;9(8):861-6. https://doi.org/10.1007/s11869-016-0442-z
Sarwar U, Nicolaou M, Khan MS, Tiernan E. Air-freshener burns: a new paradigm in burns etiology?. International journal of preventive medicine. 2011 Oct;2(4):291.
Dodson RE, Nishioka M, Standley LJ, Perovich LJ, Brody JG, Rudel RA. Endocrine disruptors and asthma-associated chemicals in consumer products. Environmental health perspectives. 2012 Jul;120(7):935-43. https://doi.org/10.1289/ehp.1104052
Kwon JT, Lee M, Seo GB, Kim HM, Shim I, Lee DH, Kim T, Seo JK, Kim P, Choi K. Cytotoxic effects of air freshener biocides in lung epithelial cells. Natural product communications. 2013 Sep;8(9):1934578X1300800929. https://doi.org/10.1177/1934578X1300800929
Steinemann A. Health and societal effects from exposure to fragranced consumer products. Preventive medicine reports. 2017 Mar 1;5:45-7. https://doi.org/10.1016/j.pmedr.2016.11.011.
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